Publications

2024

Electrochemical Conversion of CO2 to Methyl Formate in a Flow Electrolyzer with Mixed Propylene Carbonate/Methanol Catholyte
Sandesh Uttarwar, Dillon Hofsommer, Hartman, C., Francois Nkurunziza, Manu Gautam, Paxton, W.F., Craig Grapperhaus, and Joshua Spurgeon, 2024, submitted.

Understanding Electrochemical CO2 Reduction through Differential Electrochemical Mass Spectrometry
Manu Gautam, Francois Nkurunziza, Baleeswaraiah Muchharla, Bijandra Kumar, and Joshua Spurgeon, 2024, submitted.

Reactive Capture and Electrochemical Conversion of CO2 with Ionic Liquids and Deep Eutectic Solvents
Saudagar Dongare, Muhammad Zeeshan, Ahmet Safa Aydogdu, Ruth Dikki, Samira F. Kurtoğlu-Öztulum, Oguz Kagan Coskun, Miguel Munoz, Avishek Banarjee, Manu Gautam, R. Dominic Ross, Jared Stanley, Rowan S Brower, Robert Sacci, Jesús M. Velázquez, Jenny Y. Yang, Christopher Hahn, Seda Keskin, Carlos G. Morales Guio, Alper Uzun, Joshua M. Spurgeon, and Burcu Gurkan, Chemical Society Reviews, 2024, accepted.

Synergistic effects of the electric field induced by imidazolium rotation and hydrogen bonding in electrocatalysis of CO2
Oguz Kagan Coskun, Zeynep Bagbudar, Vaishali Khokhar, Saudagar Dongare, Robert E. Warburton, and Burcu Gurkan, 2024, submitted.

Decoding CO2 Electrochemical Commercialization Pathways: A Concise Review on Experimental Frontiers and Techno-Economic Analysis
Bijandra Kumar, Baleeswaraiah Muchharla, Moumita Dikshit, Saudagar Dongare, Kapil Kumar, Burcu Gurkan, and Joshua Spurgeon, 2024, submitted.

Importance of Site Diversity and Connectivity in Electrochemical CO Reduction on Cu
Chansol Kim, Nitish Govindarajan, Sydney Hemenway, Junho Park, Anya Zoraster, Calton Kong, Rajiv Prabhakar, Joel Varley, Hee-Tae Jung, Christopher Hahn, and Joel Ager, ACS Cataysis, 2024, 14, 5, 3128–3138. DOI: 10.1021/acscatal.3c05904
Highlighted in Nature Energy: Gallagher, J. Delivery of CO. Nat Energy 9, 232 (2024). https://doi.org/10.1038/s41560-024-01495-w

Direct Electrochemical Reduction of Ammonium Carbamate on Transition Metal Surfaces: Finding Activity and Stability Descriptors beyond those for CO2 Reduction
Jounghwan Choi, Shawn Chiu, Avishek Banerjee, Robert L. Sacci, Gabriel M. Veith, Chantal Stieber, Christopher Hahn, Anastassia N. Alexandrova, and Carlos G. Morales-Guio, 2024, submitted. Preprint available: https://chemrxiv.org/engage/chemrxiv/article-details/659aff8a66c1381729ee60bb

Understanding the electrode-electrolyte interfaces of ionic liquids and deep eutectic solvents
Oguz Kagan Coskun, Miguel Munoz, Saudagar Dongare, William Dean, and Burcu Gurkan, Langmuir, 2024, 40, 7, 3283–3300. DOI: 10.1021/acs.langmuir.3c03397

Accelerated screening of carbon dioxide capture by liquid sorbents
Ryan J. R. Jones, Yungchieh Lai, Kevin Kan, Dan Guevarra, Joel A. Haber, Natalia M. Ramirez, Alessandra Zito, Clarabella Li, Jenny Y. Yang, Aaron M. Appel, and John M. Gregoire, Digital Discovery, 2024, 3, 674-680. DOI: 10.1039/D3DD00232B

Key Experimental Considerations When Evaluating Functional Ionic Liquids for Combined Capture and Electrochemical Conversion of CO2
Saudagar Dongare, Oguz Kagan Coskun, Eda Cagli, Jared S Stanley, Ab Qayoom Mir, Rowen S Brower, Jesús M Velázquez, Jenny Y Yang, Robert L Sacci, and Burcu Gurkan, Langmuir, 2024. DOI: 10.1021/acs.langmuir.3c03828

Composition-Property Relationships of Choline Based Eutectic Solvents: Impact of the Hydrogen Bond Donor and CO2 Saturation
Ruth Dikki, Vaishali Khokhar, Muhammad Zeeshan, Sanchari Bhattacharjee, Oguz Kagan Coskun, Rachel Getman, Burcu Gurkan, Green Chemistry, 2024, 26, 6, 3441-3352. DOI: 10.1039/D3GC04905A

Maximum and Comparative Efficiency Calculations for Integrated Capture and Conversion CO2
Jenny Y. Yang and Aaron M. Appel, ACS Energy Letters, 2024, 9, 2, 768-770. DOI: 10.1021/acsenergylett.3c02489

2023

Tailoring Electrochemical CO2 Reduction on Copper by Reactive Ionic Liquid and Native Hydrogen Bond Donors
Oguz Kagan Coskun, Saudagar Dongare, Brian Doherty, Aidan Klemm, Mark Tuckerman, and Burcu Gurkan, Angew. Chem. Int. Ed., 2023, e202312163.

Selective Electrochemical Reduction of Nitrous Oxide to Dinitrogen with an Iron Porphyrin Complex
Jared S. Stanley, Xinran S. Wang, and Jenny Y. Yang, ACS Catalysis, 2023, 13 (19), 12617-12622. DOI: 10.1021/acscatal.3c02707

A Bifunctional Ionic Liquid for Capture and Electrochemical Conversion of CO2 to CO over Silver
Saudagar Dongare, Oguz Kagan Coskun, Eda Cagli, Kevin Y. C. Lee, Guodong Rao, R. David Britt, Louise A. Berben, and Burcu Gurkan, ACS Catalysis, 2023, 13 (12), 7812-7821. DOI: 10.1021/acscatal.3c01538

Acknowledgements: This material is based upon work performed by the Center for Closing the Carbon Cycle, which is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences Energy Frontier Research.